I loved Chuck. It was hilarious. Phoenix I believe has been enjoying Orange is the New Black. If you are into anime I can recommend a shit load more.
ie Black Butler, Fate Zero, Kaze No Stigma, The Devil is a Part Timer, Gurren Laggan, Kill La Kill,
If you have Hulu Plus
Bad Judge, Gotham, Flash,
for anime Naruto Shippuden, Bleach, Naruto, One Piece,
For Cartoon: Fugget About it.